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2026 , Vol. 2 >Issue 1: 15 - 24

DOI: https://doi.org/10.1007/s44275-025-00031-6

ORIGINAL ARTICLE

Evaluating the protective efficacy of polymer encapsulation layer for perovskite solar cells under space radiation exposure

  • Hongkai Zhang ,
  • Kang Wei ,
  • Guodong Zhang ,
  • Yuqing Yue ,
  • Yuchuan Shao ,
  • Bin Wei ,
  • Wei Shi ,
  • Yifan Zheng
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  • 1 School of Microelectronics, Shanghai University , Shanghai 200444, China
    2 Key Laboratory of Materials for High-Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
    3 School of Mechatronic Engineering and Automation, Shanghai University , Shanghai 200072, China
    4 Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai 200072, China
Hongkai Zhang is a master’s student at Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences (CAS) and Shanghai University (SHU). He received his B.S. degree from Shanghai Dianji University (SDJU) of Material Forming and Control Engineering in 2018. His research focuses on perovskite solar cells.
Kang Wei is a master’s degree candidate at Shanghai Institute of Optics and Fine Mechanics (SIOM) and University of Chinese Academy of Sciences (UCAS). He received his bachelor’s degree from Nanjing Tech University in 2019. His research focuses on perovskite optoelectronic devices.
Guodong Zhang received his bachelor’s degree and master’s degree from China University of Petroleum in 2017 and 2020, respectively. He received his Ph.D. degree from Shanghai Institute of Optics and Fine Mechanics (SIOM) in 2023. He has long been engaged in the research of photovoltaic technology related to organic materials and perovskite materials.
Yuqing Yue is a master’s student at Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences (CAS) and Shanghai University (SHU). She received her B.S. degree from Guilin University of Electronic Science and Technology in 2018. Her research focuses on perovskite solar cells.
Yuchuan Shao is a researcher at Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences. He received his master’s degree from Shanghai Institute of Optics and Fine Mechanics (SIOM) in 2012. He received his Ph.D. from University of Nebraska-Lincoln in 2016. He completed his postdoctoral studies with a postdoctoral fellowship at Yale University (2016–2017) and University of North Carolina at Chapel Hill (2018). His research focuses on flexible solar cells, high-efficiency perovskite quantum dot light-emitting diodes, and perovskite X-ray detectors.
Bin Wei is a professor at Shanghai University, China. He received his bachelor of science and master of science degrees from Peking University in 1990 and 1993, respectively. He received his Ph.D. from University of Tsukuba, Japan in 2002 and doctor of engineering from Shinshu University in 2006. He was a lecturer at Peking University, a special researcher at the Japan Society for the Promotion of Science and Technology, and a visiting professor at Beihang University. His research focuses on organic light-emitting diodes (OLEDs) and organic field effect transistors (OFETs).
Wei Shi is a professor at Shanghai University, China. She received her Ph.D. in engineering from University of Electronic Science and Technology of China (USTC) in 2017, and received the Outstanding Doctoral Dissertation Award from the Chinese Institute of Electronics (CIE) in 2019. She completed her postdoctoral research at the Institute of Chemistry, Chinese Academy of Sciences, 2018–2021, under the Postdoctoral Innovative Talent Support. Her main research interests include organic light-emitting diodes (OLEDs) and interface modification of organic field effect transistor (OFET) devices and OFET-based biological and gas sensors.
Yifan Zheng is now an associate professor at Shanghai Institute of Optics and Fine Mechanics (SIOM, CAS). He received his Ph.D. degree in optical engineering from University of Electronic Science and Technology of China, and then completed his postdoctoral research at the State Key Laboratory of Artificial Microstructure and Mesoscopic Physics, Department of Physics, Peking University. His research interests are focused on the design and optimization of the organic and perovskite optoelectronic devices.
*Wei Shi (shiwei@shu.edu.cn)
*Yifan Zheng (yifanzheng@siom.ac.cn)

Received date: 2025-01-10

  Revised date: 2025-02-22

  Accepted date: 2025-03-03

  Online published: 2025-10-23

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Abstract

Flexible perovskite solar cells (FPSCs) have demonstrated considerable potential as a next-generation photovoltaic technology for space applications. However, their performance stability in space radiation environments remains a critical challenge. This paper proposes a performance evaluation strategy for FPSCs subjected to space irradiation damage. This strategy integrates a radiation damage model with a multi-physics field-coupled optoelectronic device performance simulation methodology, systematically assessing the protective efficacy of four commonly utilized polymer encapsulants under low Earth orbit proton radiation exposure. The results show that polyimide (PI) is better at blocking protons at all energy levels, making it the best encapsulation material for FPSCs. Furthermore, COMSOL fitting calculations reveal that PI-encapsulated devices exhibit sustained high performance following radiation exposure, underscoring their remarkable stability in terms of opto-electronic performance. This study provides a robust theoretical foundation and technical support for the protective design of spacecraft components and serves as a significant reference for the selection of appropriate encapsulation materials for future space applications.

Key words： Proton irradiation; Space photovoltaics; Encapsulation; Radiation damage simulation; COMSOL

Cite this article

Hongkai Zhang , Kang Wei , Guodong Zhang , Yuqing Yue , Yuchuan Shao , Bin Wei , Wei Shi , Yifan Zheng . Evaluating the protective efficacy of polymer encapsulation layer for perovskite solar cells under space radiation exposure[J]. Moore and More, 2026 , 2(1) : 15 -24 . DOI: 10.1007/s44275-025-00031-6

References

[1] Ding G , Zheng Y , Xiao X , Cheng H , Zhang G , Shi Y et al (2022) Sustainable development of perovskite solar cells: keeping a balance between toxicity and efficiency. J Mater Chem A 10(8159-8171). https://doi.org/10.1039/d2ta00248e
[2] Sun M , Zheng Y , Shi Y , Zhang G , Shao Y (2022) Low-intensity–low-temperature stability assessment of perovskite solar cells operating on simulated Martian surface conditions. Phys Chem Chem Phys 24(17716-17722). https://doi.org/10.1039/d2cp01450e
[3] Guo X , Chen X , Li Q , Zhang G , Ding G , Li F et al (2023) High-efficiency wide-bandgap perovskite solar cells for laser energy transfer underwater. Energy Technol 11: 2300083. https://doi.org/10.1002/ente.202300083
[4] Wang H , Zheng Y , Zhang G , Wang P , Sui X , Yuan H et al (2023) In situ dual-interface passivation strategy enables the efficiency of formamidinium perovskite solar cells over 25%. Adv Mater 36: 2307855. https://doi.org/10.1002/adma.202307855
[5] Zhang Y , Shi Y , Wang H , Zhang G , Pan A , Xiang L et al (2024) Harmonizing efficiency and bending performance in flexible perovskite solar cells through annealing duration optimization. Energy Technol 12: 2301316. https://doi.org/10.1002/ente.202301316
[6] Huan ZH , Zheng YF , Wang KP , Shen Z , Ni W , Zu J et al (2024) Advancements in radiation resistance and reinforcement strategies of perovskite solar cells in space applications. J Mater Chem A Mater 4: 1910-1922. https://doi.org/10.1039/d3ta06388g
[7] Tu Y , Wu J , Xu G , Yang X , Cai R , Gong Q et al (2021) Perovskite solar cells for space applications: progress and challenges. Adv Mater 33: 2006545. https://doi.org/10.1002/adma.202006545
[8] Lang F , Eperon GE , Frohna K , Tennyson EM , Al-Ashouri A , Kourkafas G et al (2021) Proton-radiation tolerant all-perovskite multijunction solar cells. Adv Energy Mater 11: 2102246. https://doi.org/10.1002/aenm.202102246
[9] Parkhomenko HP , Solovan MM , Sahare S , Mostovyi AI , Aidarkhanov D , Schopp N et al (2023) Impact of a short-pulse high-intense proton irradiation on high-performance perovskite solar cells. Adv Funct Mater 34: 2310404. https://doi.org/10.1002/adfm.202310404
[10] Kirmani AR , Durant BK , Grandidier J , Haegel NM , Kelzenberg MD , Lao YM et al (2022) Countdown to perovskite space launch: guidelines to performing relevant radiation-hardness experiments. Joule 6: 1015-1031. https://doi.org/10.1016/j.joule.2022.03.004
[11] Kirmani AR , Ostrowski DP , VanSant KT , Byers TA , Bramante RC , Heinselman KN et al (2023) Metal oxide barrier layers for terrestrial and space perovskite photovoltaics. Nat Energy 8: 191-202. https://doi.org/10.1038/s41560-022-01189-1
[12] Malinkiewicz O , Imaizumi M , Sapkota SB , Ohshima T , ?z S (2020) Radiation effects on the performance of flexible perovskite solar cells for space applications. Emerg Mater 3: 9-14. https://doi.org/10.1007/s42247-020-00071-8
[13] Kum TB , Kirmani AR (2024) Critical role of low-energy protons in radiation testing of perovskite space solar cells. ACS Photonics 12: 439-446. https://doi.org/10.1021/acsphotonics.4c01818
[14] Ramasamy E , Karthikeyan V , Rameshkumar K , Veerappan G (2019) Glass-to-glass encapsulation with ultraviolet light curable epoxy edge sealing for stable perovskite solar cells. Mater Lett 250: 51-54. https://doi.org/10.1016/j.matlet.2019.04.082
[15] Yoon GW , Jo BH , Boonmongkolras P , Han GS , Jung HS (2025) Perovskite tandem solar cells for low Earth orbit satellite power applications. Adv Energy Mater 15: 2400204. https://doi.org/10.1002/aenm.202400204
[16] Nguyen D-T , Walter D , Weber KJ , Duong T , White TP (2023) Simulating proton radiation tolerance of perovskite solar cells for space applications. Adv Energy Sustainability Res 4: 2300085. https://doi.org/10.1002/aesr.202300085
[17] Xue B , Zhang L , Li Z , Jiang W , Liang Y , Liu N et al (2022) Property degradation of mixed-cation perovskite films and solar cells irradiated with protons. Nucl Instrum Methods Phys Res B 526: 29-35. https://doi.org/10.1016/j.nimb.2022.06.012
[18] Angmo D , Yan S , Liang D , Scully AD , Chesman ASR , Kellam M et al (2024) Toward rollable printed perovskite solar cells for deployment in low-Earth orbit space applications. ACS Appl Energy Mater 7: 1777-1791. https://doi.org/10.1021/acsaem.3c02761
[19] Cheimarios N , To D , Kokkoris G , Memos G , Boudouvis AG (2021) Monte Carlo and kinetic Monte Carlo models for deposition processes: a review of recent works. Front Phys 9: 631918. https://doi.org/10.3389/fphy.2021.631918
[20] Hoseini M , Hamidi S , Mohammadi A (2024) The use of the SRIM code for calculating radiation damage induced by γ-rays. Pramana 38: 31. https://doi.org/10.1007/s12043-023-02708-9
[21] Durant BK , Afshari H , Singh S , Rout B , Eperon GE , Sellers IR (2021) Tolerance of perovskite solar cells to targeted proton irradiation and electronic ionization induced healing. ACS Energy Lett 6: 2362-2368. https://doi.org/10.1021/acsenergylett.1c00756
[22] Brus VV , Lang F , Bundesmann J , Seidel S , Denker A , Rech B et al (2017) Defect dynamics in proton irradiated CH 3NH 3PbI 3 perovskite solar cells . Adv Electron Mater 3: 1600438. https://doi.org/10.1002/aelm.201600438
[23] Ho-Baillie AWY , Sullivan HGJ , Bannerman TA , Talathi HP , Bing J , Tang S et al (2021) Deployment opportunities for space photovoltaics and the prospects for perovskite solar cells. Adv Mater Technol 7: 2101059. https://doi.org/10.1002/admt.202101059
[24] Agarwal S , Lin Y , Li C , Stoller RE , Zinkle SJ (2021) On the use of SRIM for calculating vacancy production: quick calculation and full-cascade options. Nucl Instrum Methods Phys Res B 503: 11-29. https://doi.org/10.1016/j.nimb.2021.06.018
[25] Tregnago G (2024) Tolerance testing. Nat Energy 9: 235. https://doi.org/10.1038/s41560-024-01498-7
[26] Romano V , Agresti A , Verduci R , D’Angelo G (2022) Advances in perovskites for photovoltaic applications in space. ACS Energy Lett 7: 2490-2514. https://doi.org/10.1021/acsenergylett.2c01099
[27] Lang F , Jo?t M , Bundesmann J , Denker A , Albrecht S , Landi G et al (2019) Efficient minority carrier detrapping mediating the radiation hardness of triple-cation perovskite solar cells under proton irradiation. Energy Environ Sci 12: 1634-1647. https://doi.org/10.1039/c9ee00077a
[28] Lang F , Nickel NH , Bundesmann J , Seidel S , Denker A , Albrecht S et al (2016) Radiation hardness and self-healing of perovskite solar cells. Adv Mater 28: 8726-8731. https://doi.org/10.1002/adma.201603326
[29] Huang H , Qian W , Dai C , Zhao Y , Liang Y , Lei R et al (2024) Unraveling the degradation and air-induced healing mechanisms of Halide perovskites under proton irradiation. ACS Appl Mater Interfaces 16: 65108-65118. https://doi.org/10.1021/acsami.4c16818
[30] Shin J , Baek K-Y , Lee J , Lee W , Kim J , Jang J et al (2021) Proton irradiation effects on mechanochemically synthesized and flash-evaporated hybrid organic-inorganic lead halide perovskites. Nanotechnology 33: 065706. https://doi.org/10.1088/1361-6528/ac34a7
[31] Zhang T , He Q , Yu J , Chen A , Zhang Z , Pan J (2022) Recent progress in improving strategies of inorganic electron transport layers for perovskite solar cells. Nano Energy 104: 107918. https://doi.org/10.1016/j.nanoen.2022.107918
[32] Li H , Liu S (2024) Revolutionary SAMs: transforming inverted perovskite solar cells. J Mater Chem A 12: 9929-9932. https://doi.org/10.1039/d4ta00962b
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